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[ReCl(CO)(3)(Bn-pyta)] crystallized in the monoclinic system with space group P2(1)/n. Bn-pyta ligand coordinates with the nitrogen atoms of the 2-pyridyl group.
Continue to access RSC content when you are not at your institution. Follow our step-by-step guide. China E-mail: dumiao public. It is interesting to note that the building block pyta anion exhibits different configurations and coordination modes in the solid structures of complexes 1—6. These results indicate that the versatile nature of this flexible ligand , together with the coordination preferences of the metal centers, play a critical role in construction of these novel coordination polymers or supramolecules.
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Please be aware that pubs. During this time, you may not be able to log-in to access your subscribed content, purchase single articles, or modify your e-Alert preferences. We appreciate your patience as we continue to improve the ACS Publications platform. Elevated-temperature scanning tunneling microscopy imaging and large-scale density functional theory calculations are employed to map out the chemical identity and stability of atomic oxygen functionalities in different regions of graphene supported on ruthenium The terminally bonded enolate species are found to be strongly preferred over bridge-bonded epoxy groups in graphene regions that are close to the underlying metal.
The effect of outer-sphere environment on alkene epoxidation catalysis using an organic hydroperoxide oxidant is demonstrated for calixarene-TiIV single-sites grafted on amorphous vs crystalline delaminated zeotype UCB-4 silicates as supports. A chelating calixarene macrocyclic ligand helps enforce a constant TiIV inner-sphere, as characterized by UV—visible and X-ray absorption spectroscopies, thus enabling the rigorous comparison of outer-sphere environments across different siliceous supports.
Polyketides are a large class of bioactive natural products with a wide range of structures and functions.
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Rizospirillum is a biostimulant that contains Azospirillum brasilense , a species of bacteria that enhances plant growth. Rizospirillum bacteria colonize the rhizosphere and promote plant development by means of biological nitrogen fixation, nutrient solubilization and phytohormones such as auxins , gibberellins and cytokinins release, allowing for a higher crop yield potential.
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